Showing posts with label ABS. Show all posts
Showing posts with label ABS. Show all posts

Monday 10 January 2011

ABS on PETG

I have been using PET tape on my heated bed for a long time now. It works very well as long as I clean it with acetone about every 100 hours. It does need a high temperature (145°C) for the first layer with some types of ABS though .

It seems to last forever, the only failure mode is that large thick objects with sharp corners can defeat the adhesive and raise blisters at the corners near the edge of the bed. I solve that by building little heat shields to keep the corners warm. I am always on the lookout for something better though. It would be nice to get rid of the lines where the tape butts against itself.

A friend gave me a sheet of 1mm thick PETG to try. I clipped it onto my heated bed, and thinking it would behave like PET tape, I ran a build using the same temperatures.


Big mistake, PET has a glass transition at 75°C so it went soft and floppy. The object stuck to it very well and was hard to remove, but after getting a knife under one corner, it peeled cleanly. However it left an impression in the PETG.


The base of the object is flat but the filaments are more ridged because they sank into the sheet rather than being squashed.


When the sheet cooled down it warped badly, so that was the end of that experiment. I did have a small offcut though so I tried again at 70°C.


This time the object warped badly. It stayed stuck to the PETG but it warped the sheet. The adhesion was less and the object was easily peel-able. The PETG warped where the object was but the rest of it stayed flat. The heat of the object must have been enough to tip it over its glass transition locally. It left an impression, but not as deep as the first time.



The filaments on the bottom were squashed tighter, not as smooth as when using tape.


So a failed experiment. It is a shame because at high temperatures it bonds very well but, unlike PC, it still peels, but it is no good if it doesn't remain rigid. Wikipedia does say that PETG has a lower melting point than PET. It doesn't mention how it affects Tg, but it gives the Tg of PET as 75°C. Odd then that PET tape doesn't go soft at 75°C. My next trial will be Mylar, which is another form of PET (BoPET).

Sunday 12 September 2010

Some corners like it hot

Large objects with sharp corners, such as the Mendel z-leadscrew-base, produce enough stress to form a blister in the PET tape on my heated bed. These can only be flattened again by pricking the tape. I can't understand how air gets in and cannot get out again, but that is what seems to happen.

The blisters leave a small indentation in the object's base. It is only an aesthetic problem because the base remains flat, i.e. it doesn't rock on a flat surface.

Sometimes the blister allows the corner to peel from the bed towards the end of a build, allowing the corner to curl upwards a little. Generally I can avoid that by cleaning the bed with acetone before problem builds. I also use hexagonal infill on those parts and only two solid layers rather than three in an attempt to reduce the stress. When I design my own parts I round the corners, where possible, to prevent such problems.

A solution may be to use a sheet of PET rather than PET tape, but then you need to find a way of holding it down. One thing I have noticed though is that when I build a bed with four of the z-brackets closely packed the corners on the inside don't blister or lift. That must be because the air around them is hotter. As an experiment I added some little plastic walls to the build to act as baffles to keep the heat in as the bed moves through cooler air.


These have a 5mm thick base to help keep the tape flat and are 1mm away from the edge of the object. They work well and stop the blisters forming at the corners. They are very similar to Forrest's apron technique but their primary function is thermal rather than mechanical. A more general technique would be to build a thin wall all the way around the perimeter of the objects to cocoon them. I expect that would only need to be one filament thick and perhaps might give a similar effect to having a heated build chamber.

Saturday 3 July 2010

ABS on PC

My last heated bed ran for a long time but it finally went pop on Mendel print number 15. The TO220 resistors developed a short to earth about half way though an 8 hour overnight build. It took out a 5 Amp mains fuse and destroyed the 4 Amp solid state relay that was controlling it.

Clearly the cheap TO220 resistors are just not suitable for abusing as heating elements, so I went back to using aluminium clad resistors. The disadvantage is that they are higher profile and need two accurately drilled mounting holes, but they are a lot more robust and cheaper. The more expensive TO220 resistors I used on HydraRaptor are still going strong, but there is nothing to suggest that they are any better in their spec. It is the tab insulation that breaks down though, so it could be just the fact that the voltage is much lower on HydraRaptor.

I have used the Tyco THS10 series at temperatures up to 240°C and not had any fail yet. They are not rated for mains voltage though, so I moved up to THS15 series which are. They are slightly taller, which doesn't actually matter because I use 20mm stand-offs, so there is still sufficient gap. The mounting holes will take an M2.5 screw, but I didn't have any to hand, so I drilled them out for M3. There is just enough room for a screw head with an integral washer, a standard washer would not fit.

I have run the THS10 at about twice their rating so I did the same with these: 9 × 22Ω in series gives a total power of 290W at 240V. That gives a warm-up time of about 4 minutes to 140°C. My extruder takes longer to get to 255°C, so I set them both off together so that the bed has enough time at its steady state temperature for the nylon pillars to expand fully.



The white PTFE clamp is where I attach the thermocouple. The device wrapped in Kapton tape is a 190°C thermal cut-out to prevent melt down if the firmware crashes or the solid state relay goes short circuit. The mains wire has PTFE insulation to handle the temperature. Since the wiring is exposed it should really have an extra layer of insulation to be considered safe, but I am not about to stick my fingers under a hot bed so I didn't bother. If you have children or animals, or are completely risk averse, then you probably should.

I haven't put any magnets on this one yet as I haven't been making use of the ones on the last bed since I started using white ABS on PET tape. The objects mainly come loose when they cool down and are easily removed without having to remove the steel plate and bend it.

ABS on PET tape works well. The grip level seems to degrade much more slowly than Kapton does. After lots of use it becomes easier to remove objects, but then the amount of grip is not quite enough for some parts. I can make most of the Mendel parts time after time, but I have problems with a few. The outer corners lift slightly towards the end of the build of the large Z brackets when the PET is old and I am building more than one at a time.



Not easy to see, but the bottom right corner has lifted by about 0.5mm. It makes no difference to the function of the part but I like to get them completely flat.



At the opposite end of the scale I have problems with the bed springs and the X 360 Z bearing plates. These are very tall compared to their footprint, so as the nozzle bushes past the top of the objects they often ping off the bed due to the small contact area and the high leverage. When the PET is old I have about a 30% reject rate with these unless I do them one at a time.

I had a 5mm sheet of polycarbonate that I have been meaning to try as a bed material for some time. I think that is what is used on commercial machines. It has a high melting point (267°C), so will not melt when the hot filament lands on it. It also has a high glass transitions (150°C) so shouldn't soften on a heated bed.

I clamped it to the aluminium bed with some bulldog clips.



I tried it cold to start with but the ABS did not stick so I tried it at 140°C next. I made a test shape that I am using to research hole shrinkage. It stuck so well I broke it trying to get it off.



I had to use a chisel to get the rest off. Strangely, although the ABS is extruded below the melt point of the PC, so it can't form a diffusion weld, it forms a stronger bond with the PC than to itself.

I dropped the initial bed temperature to 50°C which seemed to be the lowest I could get the first layer outline to stick properly. After the first layer I set the bed temperature to 90°C to reduce the warping stress in the ABS. These are temperatures on the underside of the aluminium, so the top surface of the PC will be something like 15-20°C lower.



I made these tall objects that tend to come unstuck from PET. These held well, in fact, when I removed them, most of the springs and one of the bearing plates left their bottom layer behind. Not really a big problem, the bottom layer becomes a minimalist raft!

For general production I went back to PET tape. I covered a sheet of 1.5mm thick stainless steel and clamped it down with more bulldog clips. I can swap it with a sheet of glass if I need to do PLA. The steel seems to be strong enough to stay flat in the middle when clamped at the edge.

Monday 24 May 2010

Black and White

I bought some new ABS filament from reprapsource.com as it is a reasonable price, the postage from Germany is not too bad and being in the EU there are no customs charges, so it does not get held to ransom by Parcel Force for their ridiculous handling charge.

The advert does not state a colour so I assumed it would be natural, however when it came it wasn't like any ABS I had encountered before. Natural ABS is cream coloured and opaque. This was white and a bit translucent. At first I though it was HDPE, but when bent it bruised, which is a characteristic of ABS.

I ran it first in HydraRaptor. The only issue I had was that it didn't want to stick to the PET tape I was using until I raised the bed temperature to 140°C for the first layer and extruded at 250°C. For subsequent layers I revert to the bed at 110°C and filament at 240°C.

The objects produced look nice in white and seem to be harder than those made in natural. I don't think it is simply pigmented ABS, I think it is a different formulation.

My impressions of using PET tape instead of Kapton tape is that it doesn't seem to give as much grip as new Kapton, but it doesn't degrade. I can make most things on it with HydraRaptor without any warping at all, but Mendel bed springs tend to come unstuck. This is because they are relatively tall and have very little contact area with the bed. If the extruder hits a slight blob on a high layer it will snap the part off. Sometimes the loose part hits another part and starts a chain reaction where they all fall off.

When doing raft-less builds on PET or Kapton it is essential that the first layer outline sticks perfectly and has no gaps in it, especially at the corners. If the first layer is too high it obviously doesn't stick and takes short cuts across the corners. If it is too low it also lifts at the corners though. What happens is that the filament becomes squashed into a flat ribbon. When that tries to bend around a sharp corner the outside has to stretch but instead it lifts and folds over inwards. A difference in z-value of 0.05mm can make all the difference. Increasing the temperature also helps to make the plastic bend around corners. If a corner does not stick perfectly then after two or three layers it will curl up at an angle of about 45°. This effect is not like the corner warping you get on a cold bed. It is much more localised and extreme. Small objects tend to come off during the build if a corner lifts.

With the natural ABS I was using before on Kapton it was far less critical. Objects stuck so well I had to remove them with a hammer or use a flexible bed. With white ABS on PET tape the objects can be removed more easily. Sometimes they just come free when they are cooled.

When I tried the new ABS in my Mendel it took a lot more tweaking to get it to work. The first issue was that I had to increase the feed rate by about 18% relative to what I was using for PLA. My theory is that being softer it presses further into the threaded pulley and so sees a smaller pulley diameter. The hobbed M8 bolt has an internal radius of only about 5mm. The drive pulley on HydraRaptor is about twice that diameter and seems give more grip on softer plastics and doesn't need the 18% bodge factor when switching from PLA to ABS. I just tell it the filament diameter and it just works.

The next problem I had was that holes tended to shrink inwards and not meet the infill as you can see on this piece.



I also find PLA has a tendency to do this on my Mendel but not on HydraRaptor. For a sanity check I built the same object from the same g-code with black ABS.

Notice how much bigger the holes are.

When I was flushing the black out again with the white I noticed that the white had far more die swell and was coming out at about 0.7mm. The black was only about 0.55mm. This means that to extrude at 0.5mm the white is being stretched a lot more, which accounts for why the holes shrink inwards. To test this hypothesis I ran the same g-code again scaling up all the coordinates by 0.6/0.5. This produced a bigger object but the holes are much better.



I then re-sliced the object for 0.6mm filament and that also printed correctly.



So it seems that the white ABS has more die swell than natural or black. In that respect it also reminds me of HDPE. For some reason HydraRaptor is not affected and seems to have less die swell despite having a smaller nozzle, which normally gives more die swell in relative terms because the pressure is higher.

The other thing I discovered is that black ABS does not stick well to PET. It seems a bit greasy.

So with a 0.5mm nozzle if have to build objects at 0.6mm when using white ABS in my Mendel, but with a 0.4mm nozzle on HydraRaptor I can build at 0.375mm or 0.4375mm no problem and holes do not shrink excessively. I am not sure what the difference is, perhaps the length of the nozzle aperture.

Sunday 10 January 2010

Golden wonder

My first attempt at extruding ABS onto hot Kapton had "all the stops pulled out" to make it stick, i.e. 120°C bed, nozzle height 0.1mm too low, very slow outline and infill on the first layer (4mm/s). The adhesion was very good so I decided to back off a bit. It is not a good idea to change more than one thing at a time but I did anyway. I got rid of the -0.1mm Z offset and sped up the first layer infill to 32mm/s, leaving the outline at 4mm/s. I also dropped the bed temperature to 80°C. That was too low, the corners lifted about 1mm during the build, but I think the part will still be usable.



The base is still glossy but you can see and feel some valleys between the extrusion "lanes". The next test was a binary chop with the bed at 100°C.



This is perfectly flat, even when off the bed for a day, but the extrusion lanes are still noticeable. The next test was at 110°C.



The extrusion lanes are gone in most places but a few are just visible. The first one that I did at 120°C has no extrusion lanes on it all, just some very slight graining from the Kapton tape that you can also see on the picture above. The tape lines and grain go from bottom right to top left. The extrusion infill slopes bottom left to top right and is only visible on the right hand side of the object. I think perhaps Z has to be a bit lower to get rid of them completely, but it is only important if you want to make something aesthetic, like an instrument panel, for example.

Of course there are the tape join marks. I used unbranded polyimide as it seems to be about half the price of branded Kapton. I got it from here, which is very cheap and free shipping if you don't mind waiting a while. You can get polyimide tape up to 250mm wide, but it is always on a 33m roll, so it gets very expensive. I have ordered a 150mm roll to cover the working area of HydraRaptor's build table. It was £53.71 from here, so very expensive, but a small price to pay for perfection! I don't know when it will arrive as post is a nightmare at the moment. I am still waiting for things from the 17th of December. Parcels are not being delivered because of the snow, so you have to go and collect them, but several letters and packets seem to have disappeared.

Here are all the tests side by side, notice the colour change with temperature, it is a bit exaggerated on the photo : -



I now have a full set of Mendel vertexes including two that I made in PLA that warped slightly (on a cold bed). I moved onto something more ambitious on the warping front: the Mendel x-carriage-lower_1off part. I don't think this is printable in ABS without a heated platform, or air stream, unless you use the apron method developed by Forrest Higgs. For this test I started the bed at 120°C and dropped it to 100°C after the first layer. The logic being that 100°C seems to be enough to prevent warping, but 120°C is needed to get a perfectly smooth finish. It takes a few layers before the temperature has dropped to 100°C as I don't wait for the plate to cool down.



Unfortunately the ancient version of Skeinforge that I use gets one layer wrong on this part. The layer has the central hole missing. The filament didn't span the void very well as it is a very big void, I have no fan running and there is a lot of heat rising from the bed. That caused some filament to stick up and collide with the head. It spun round 90° unscrewing it 1/4 of a turn. Amazingly it did not leak but the nozzle hole must be slightly off centre with respect to the barrel thread, so I got an offset in X and Y above the layer that went wrong. Still, the objective was to test warping and it came out totally flat.



The corners have a dimple that looks like an air bubble, but must be something to do with them trying to lift I think. Apart from these the base is as flat as glass and had it not been for the Skeinforge bug it would have been usable straight off the bed. I cut the membrane out with a knife and drilled through the blinded holes before taking these pictures.



I tried the x-carriage-upper_1off starting the bed at 120°C for the first layer and dropping to 90°C. Again Skeinforge got it wrong, not surprising as the topology is very similar. This time I also dropped the filament temperature to 220°C, so it spanned better and the head did not get spun. A longer snout on the nozzle might be a good idea to avoid collisions with build defects.



Again here it is with the membrane removed.



The corners lifted very slightly but the rest of the base is completely flat. It doesn't rock on a flat surface like an object made on a cold bed would. In fact, the raised corners made it easier to remove from the bed.



So it looks like 100°C bed temperature is the minimum to prevent warping when using Kapton. 120°C for the first layer gives a better aesthetic finish, perhaps with a small negative z-offset. Having the object kept warm seems to allow a lower filament temperature without losing strength. I used to build at 240°C and use 0.5mm for stronger objects. I can now use 220°C and 0.4mm with no sign of de-lamination so far. The lower temperature is good because the ABS out-gasses less and so smells less.

I can't recommend Kapton on heated aluminium highly enough. It has transformed my experience building with ABS completely. I no longer need a raft, which saves a lot of plastic, time and labour to remove it. My objects can be completely flat, smooth and glossy. Together with using a geared stepper extruder drive to completely eliminate ooze it means I just print an object, remove it from the bed and it is ready to use. There is a slight meniscus of plastic around the base, which you might want to remove with a file or a knife.

It has several advantages over acrylic: -
  • Acrylic is a good insulator, so even 3mm reduces the surface temperature by about 15°C, making it take longer to warm up and harder to control.
  • It tends to warp as it has a similar glass transition temperature to ABS.
  • It can be hard to remove the object as it can be permanently welded if you deposit the ABS hot enough.
The way ABS sticks to hot Kapton is different. The Kapton does not melt at all so you don't get a weld no matter how hot the ABS is. I don't know what sort of bond it makes, but it is always peel-able.

While I have been writing this article a friend came up with a brilliant suggestion. Why not use non-adhesive Kapton film, clamp it on the table, possibly with a vacuum? When the build is finished just release it so it can be peeled off the object with ease. I realised that would enable a conveyor belt table to be made. People have suggested this would allow a machine to churn out parts unattended. E.g., stretch a band of Kapton over a heated plate and rotate it when the object is finished and has cooled. The object will then drop off the end.

I still have a couple of problems to solve with the heated bed. The heat spreads downwards and warms my X-Y table. It is not much, I haven't measured it but I would guess to mid 40's C. That is enough to expand the aluminium that the table is made from and open up a gap in the ways so that it has some play and starts rattling. I removed the foam-board to leave an air gap (the logic being that the movement of the table would generate some cooling airflow) and covered the top of the bed with aluminium foil to reflect the heat back. That helped, but not enough. I think I will need to blow cold air over the top of the table with a sheet of something like PTFE to cover the bottom of the heated bed.

The other issue is that having heat around the object rather than cold air blowing on it means that void spanning and overhangs don't work as well as they did. I think I need a jet of warmed air directed at the end of the nozzle to cool filament to freeze it quickly.

Tuesday 5 January 2010

Hot metal and serendipity

I couldn't get to work today because we had seven inches of snow during the night and a couple more today, so I had an extra day of RepRapping.

So my extruder is back working after re-fixing the thermistor with some RTV silicone. I get a degree or two more temperature swing with silicone compared to Cerastil, so not ideal, but it is workable. I think the plastic has such a high specific heat capacity and thermal resistance that it probably averages out the temperature swings anyway.

I switched to ABS to make a change from PLA as I am now able to use my 5kg spool of oval ABS that has always been two wide for my previous extruders. The bore of this one is 3.6mm, which is actually a bit on the big side for 3mm filament. I think about 3.3mm would be the best compromise.

My first experiment was to see if I could extrude directly onto my heated aluminium bed. My initial attempts failed to stick, even at 110°C, but I found that I could lay down a raft. I always cool the raft before applying the first layer of the object (I also drop the temperature of the first layer to 190°C), otherwise it welds too strongly to remove. When I cooled the raft it detached from the bed, presumably because it shrinks.

I reasoned if I could get the raft to stick then I should be able to get the object to stick. The difference is I do the first layer of the raft at 4mm/s and have the head lower than I would normally, so that the filament is squashed more. I tried making the first layer of the object at 4mm/s and a little lower than it should be. It almost worked so I upped the temperature to 120°C and tried again. This time I was able to make one of Zaggo's whistles.



When it came to making the pea it got too hot and started moving around.



Normally I would use a fan on ABS to get small items to hold their shape, but obviously blowing cold air onto a hot base is going to waste a lot of power. The fix I have in mind is to blow a very small jet of air at the same temperature as the base and aim it just below nozzle. Hopefully by keeping the jet small I can avoid the sort of power that hair dryers use. Adding the heated bed has increased the power consumption of my machine by about 50W, which has more than doubled it.

When I cooled the finished object and the bed to 40°C, by running the fan, the object simply lifted off. At 120°C the ABS is like a soft rubber or gel. It clings to the aluminium, but will peel off with very little force. When it cools it becomes completely detached.



The bottom of the object is smooth and shiny and perfectly flat. I can actually see part of one of the swirls that are on my bed if I catch it right in the light. That means the plastic takes the texture of the base, so you could pattern and texture it in the same way as injection moulds.

The next thing I tried was a Mendel vertex bracket as these are big enough to warp. It managed the outline, but when it started doing the outlines of the holes the filament failed to stick so I aborted that build.

The obvious way to get more grip is to use a sheet of acrylic as many people report that works well. I have a couple of problem with that though. Acrylic is a good insulator so the temperature control becomes more difficult. It tends to warp unless it is held down at the edges. I don't have any bolts long enough to mount it on my bed with the frame on top. I ordered some 2BA studding last year, but all the post from just before Christmas has gone missing.

I looked around for a piece of metal with some texture and found some aluminium with a satin finish painted with metal primer, from a very old experiment. It looked promising to start with: -



But it soon snagged and started ripping it up again: -



However, as you can see, I held the plate down with Kapton tape and by accident part of the object was extruded onto the tape. It stuck well to the Kapton but was peel-able. This looked extremely promising. Kapton on top of aluminium could be the perfect bed material for ABS. It looks like it will be reusable many times, as masking tape is for PLA.



The bracket stayed perfectly flat during the build. I cooled it with the fan to 40°C. It was quite difficult to remove. In the end I put a penknife under one edge and tapped it with a hammer. It came off cleanly and with a perfectly flat base with a glassy appearance.



The only blemishes are the gaps in the tape, what looks like an air bubble in the tape, and the dent from my penknife.



The base is a slightly golden colour and that extends up for the first few layers so I think the bed was a bit too hot. I had it at 120°C and the first layer at 4mm/s, so I will have to back track a bit and see if I can get away with a lower temperature and faster first layer, but this is looking very good. No warping, no raft, a cheap reusable bed material and a mirror finish.

Tuesday 3 November 2009

Hacking with Erik

Erik de Bruijn (RepRap evangelist) is in the UK at the moment visiting Salford and Nottingham universities to spread the word. Yesterday he came here to see HydraRaptor. We spent a very interesting afternoon and evening, swapping extruder ideas, comparing objects we had made, and doing a couple of very successful experiments.

The first was something I had been wanting to try for a long time, and that was reversing the extruder drive to stop ooze. My latest extruder (details to follow) has a much smaller melt chamber but still has significant ooze when extruding PLA. Erik is pursuing the Bowden extruder idea, which should benefit even more from reversing.

Because my machine is controlled by Python, rather than g-code, it is very easy to try out things like this. We hacked the code to instantaneously reverse for a short distance very quickly at the end of each filament run. After moving to the start of the next run it fast forwards the same distance that it reversed before resuming the normal flow rate.

I designed a simple test shape to allow the results to be compared. It is a 15mm square with four 5mm towers at each corner. I am not using Enrique's latest Skeinforge which I think would minimise the extruder moves in fresh air to just three per layer. This is with a very old version that does the four outlines and then returns to fill each of them in.



Plenty of hairy bits showing the ooze. These can be removed easily, but what is worse is the object will be missing that amount of plastic making it weaker. This can be extreme with a thin structure which is remote from other parts of the same object.

We tried reversing 1 mm at 8 times the extrusion speed to start with. That worked but was obviously more than was needed. We tried 0.25mm which was too little and settled on 0.5mm, although a lot of that is taken up by the motor bracket flexing. I need to make it stronger.

The result was no hair at all!



A very simple fix for a problem that has used a lot of my time in the last two years.

The second experiment was something Erik wanted to try. He has discovered that PLA is soluble in caustic soda, so potentially could be used as soluble support material for ABS. The question was: can we extrude ABS onto PLA and get it to stick well enough to resist warping?

We made a 5mm thick slab of PLA 20mm wide and 40mm long, 90% fill. On top of that we extruded a 30 x 10 x 20mm block of ABS with a 25% fill.



The ABS looks very glossy so I think it may have some PLA in it. Possibly we needed to flush it through for longer. The ABS block is also a bit scrappy. The reason was that the extruder was playing up. It was leaking plastic, hence the burnt bits and the stepper motor was skipping steps leaving a deficit of plastic. This extruder had never done ABS before and still has some teething problems, but it shows that ABS will bond to PLA well enough to stop it curling.

Next we extruded a block of PLA on top of the ABS.



That also bonded well. The messy bit at the join is because HydraRaptor did its normal circuit of the object that it normally does on the first layer but it was in mid air.

To see how well they were bonded we put the PLA base in a vice and attached a small g-clamp to the PLA block on top. The g-clamp was pulled with a strain gauge until the ABS came way from the base at about 8Kg. Interestingly the first layer outline of the ABS was left on the PLA. That was deposited at 215°C whereas the infill of the first layer was at 195°C. These are the values I use for depositing ABS onto a raft, so in an object layer on top of support it would be 240°C giving a stronger bond. See Erik's writeup and video here.

So PLA looks like a good candidate for supporting ABS. They bond well and PLA is very rigid to resist warping. It can be dissolved with drain cleaner but also I expect it would be easy to peel when softened in hot water.

All in all a good day's hacking.

Thursday 20 November 2008

Hot Stuff

When I was making the chuck grip I noticed that the raft changed colour part way across the top layer of the raft.



The heater seemed to be on 100%, so it looked like the plastic was way too hot. By the time I noticed it seemed to have reached thermal equilibrium and apart from some snap crackle and pop sounds, and a bit of smoke the extruder seemed happy. I was reluctant to abort the build because it had taken about an hour to get this far.

When it finished the raft it cooled down to the right temperature and built the object. The surface of the raft has a completely different texture and it seemed easier than usual to peel off the object. Despite that, it managed to hold down what was a very big object. The shape of the object was less prone to curling than most, being a large circle (no corners to curl up) split into three segments and with a corrugated outside perimeter, which could absorb shrinkage. I need to do more experiments to know if it is beneficial to deliberately make a raft like this.

This is what the normal and hot rafts look like close up :-

And here they are under a microscope :-


To investigate further I ran a test with the heater target temperature set to 300°C and monitored the thermistor reading. It maxed out at 290°C. That is fortunate as it is just below the point where PTFE is supposed to start decomposing into poisonous substances. For some reason the PTFE holds up mechanically, I would have expected the barrel to pop out. Perhaps the ABS becomes so fluid that there is very little pressure required for extrusion. Anyway, the extruder seems happy operating at 280°C, where it just about manages to control the temperature with 96% PWM.

The filament changes from green and smooth to almost cyan and a rough texture: -


Again under the microscope the surface looks very different :-

My theory as to what is happening is that the green dye is composed of yellow and cyan dyes, and the yellow component is boiling off, disrupting the surface.

I had a go at making some objects at 240°C, 260°C and 280°C :-



It seems that 240°C is about the limit for green ABS before it starts to change colour and texture. The bottom of each object has to be at the correct temperature so it can be separated from the raft but other layers could be chosen to be different temperatures to give a stripy effect. The hot objects seem very strong and feel like they wont de-laminate in a hurry.

I don't think you can keep the plastic long at those temperatures, I found this mess under a raft. I think the temperature had gone wrong during warm up.



Initially I had no idea why my temperature control was occasionally going wrong. The thermistor is still well attached. I caught the effect with some logging and discovered that the temperature was reading about 40°C low some of the time. Touching a connector seemed to fix it. I could not find a loose connection so I just unplugged it and plugged it in again. I has been OK since. With a 10K thermistor you only need a few ohms to make a big difference at the high end.

So an interesting effect that might be exploitable for support material or aesthetic effects.